Solvolysis of 3-substituted 4-homoadamantyl methanesulphonates. Can the ?-substituent effect distinguish between classical and non-classical ion intermediates?
Author:
Publisher
Wiley
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Reference36 articles.
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2. Neighboring Carbon and Hydrogen. X. Solvolysis of endo-Norbornyl Arylsulfonates1,2,3
3. Remote inductive effects in the solvolysis of secondary and tertiary 2-norbornyl derivatives. Evidence for nonclassical stabilization of the 2-norbornyl cation
4. Inductivity and bridging in carbocations
5. The energy of the transition states and the intermediate cation in the ionization of 2-norbornyl derivatives. Where is the nonclassical stabilization energy?
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1. Wagner–Meerwein type rearrangement in 5-oxohomoadamantane series;Organic & Biomolecular Chemistry;2020
2. Generation and Reaction of a Phenyl-Substituted Cyclopentadienyl Cation Annelated with Two Homoadamantene Frameworks;The Journal of Organic Chemistry;2008-06-18
3. Synthesis of Bifunctional Polycyclic Compounds and Their Application to Mechanistic Studies of Solvolysis Reactions;Bulletin of the Chemical Society of Japan;1996-04
4. Solvolysis of [3-13C]-3,4-dimethyl-4-homoadamantyl p-nitrobenzoate. Comparison of the barriers to the Wagner-Meerwein rearrangement of the secondary and tertiary 4-homoadamantyl cations;Tetrahedron Letters;1996-02
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