Affiliation:
1. Fraunhofer R&D Center Electromobility Fraunhofer Institute for Silicate Research Neunerplatz 2 97082 Würzburg Germany
2. Julius-Maximilians-Universität Würzburg (JMU) Faculty of Chemistry and Pharmacy Chemical Technology of Materials Synthesis Röntgenring 11 97070 Würzburg Germany
Abstract
AbstractThe interplay between the internal mechanical properties and external mechanical conditions of a battery cell, e. g., Young's modulus and thickness change, has a crucial impact on the cell performance and lifetime, and thus, needs to be fully understood. In this work, 12 Ah lithium‐ion battery pouch cells were studied during cycling and aging by non‐invasive operando ultrasonic and dilation measurements. The effective Young's modulus increases and the thickness varies the most within a single cycle during the graphite transition from stage 1L to 4, at the beginning of the 2 to 1 stage transition and at the phase transition of the nickel‐rich NCM from H2 to H3. After 1000 cycles of aging, the overall effective Young's modulus of the lithium‐ion battery decreases by ∼11 %–12 % and the cell thickness increases irreversibly by ∼3 %–4 %, which is mostly related to a thicker and possibly softer, more porous solid electrolyte interphase layer.
Subject
Electrochemistry,Electrical and Electronic Engineering,Energy Engineering and Power Technology
Cited by
7 articles.
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