Facile Synthesis of Fe3O4−SiO2 Nanocomposites for Wastewater Treatment

Author:

Yaseen Muhammad1,Khan Abbas12,Humayun Muhammad3,Farooq Saima4,Shah Nasrullah1,Bibi Shaista1,Khattak Zafar A. K.5,Rehman Ata Ur6,Ahmad Sajjad7,Ahmad Shah Masood8,Bououdina Mohamed2,Ullah Habib9ORCID

Affiliation:

1. Department of Chemistry Abdul Wali Khan University Mardan Mardan 23200 Pakistan

2. Department of Mathematics and Sciences Faculty of Humanities and Sciences Prince Sultan University Riyadh 11586 Saudi Arabia

3. School of Optical and Electronic Information, Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Wuhan 430074 P. R. China

4. Department of Biological Sciences and Chemistry, College of Arts and Sciences University of Nizwa Nizwa 616 Oman

5. Institute of Chemistry Baghdad‐ul‐Jadeed Campus The Islamia University of Bahawalpur Bahawalpur 63100 Pakistan

6. Department of Chemistry Bacha Khan University Charsadda Charsadda 24420 Pakistan

7. Department of Zoology Abdul Wali Khan University Mardan Mardan 23200 Pakistan

8. Institute of Chemical Sciences University of Peshawar Peshawar 25120 Pakistan

9. Department of Engineering Faculty of Environment Science and Economy University of Exeter Exeter EX4 4QF UK

Abstract

AbstractWater constitutes ≈70–90% of the organism's body by mass and is highly important for its survival. Water contains a variety of chemical contaminants introduced by various sectors, resulting in contamination that has a direct impact on the ecosystem. Various approaches are in practice to tackle these issues. Among these, semiconductor photocatalysis appears to be the cutting‐edge technology for the degradation of wastewater contaminants. Herein, the fabrication of Fe3O4−SiO2 nanocomposite via facile co‐precipitation and Stober methods are reported. Various characterization techniques are employed for the structural elucidation, morphology, crystallinity, and stability of the as‐prepared composite. The nanocomposite is employed in catalytic and photocatalytic applications toward the removal of methylene blue (MB) and methyl orange (MO) dyes from a comparative perspective. It is observed that the composite can remove about 93% of MB and 51% of MO within 7 and 6 h, respectively. These findings indicate that the nanocomposite has a higher MB removal effectiveness than the MO. This trend can be accredited to the difference in the chemical structure of both dyes. The nanocomposite is also evaluated for antioxidant and antileishmanial activity, and it is shown to be quite effective even at very low concentrations.

Funder

Engineering and Physical Sciences Research Council

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Organic Chemistry,General Chemical Engineering

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