A New, Efficient and Direct Preparation of TlTp and Related Complexes with TlBH 4-Reference-Cited by-同舟云学术

A New, Efficient and Direct Preparation of TlTp and Related Complexes with TlBH 4

Published:2008-03 Issue:8 Volume:2008 Page:1188-1192
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Kitamura Masato¹,Takenaka Yuta¹,Okuno Tomoko¹,Holl Ralph²,Wünsch Bernhard²

Affiliation:

1. Research Center for Materials Science and Department of Chemistry, Nagoya University, Chikusa, Nagoya 464–8602, Japan, Fax: +81‐52‐789‐2261

2. Institut für Pharmazeutische und Medizinische Chemie der Westfälischen Wilhelms‐Universität Münster, Hittorfstraße 58–62, 48149 Münster, Germany

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200701366

Reference45 articles.

1. Scorpionates

2. The abbreviation rule for TpR1 R2 R3{[BH(PzR1 R2 R3)3]–} basically followed that defined by Trofimenko. Superscripted R1 R2 and R3correspond to the substituents at the C(3) C(5) and C(4) on the pyrazolyl ring respectively. The priority of C(3) is the highest followed by C(5) and then C(4). When the structure cannot be defined uniquely the carbon number is attached before the substituent: R1= R2= R3= H: Tp; R1= CH3 R2= R3= H: TpMe; R1= C6H5 R2= R3= H: TpPh; R1= R2= H R3= CH3: Tp4Me; R1= R2= CH3 R3= H: TpMe2(Tp*); R1= H R2–R3= (CH)4: Tp4Bo; R1–R3= (CH)4 R2= H: Tp3Bo; R1= H R2–R3= (CH2)4: Tp4mt4; R1–R3= (CH2)4 R2= H: Tp3mt4; R1= R2= CH3 R3= Br: TpMe2 Br(Tp*Br). The regioisomers were described by the addition of “*” to the end of the superscripts (e.g.: TpR1 R2 R3versus TpR1 R2 R3*). The discrimination of three possible regioisomers [BH(PzR1 R2 R3)2(PzR2 R1 R3)]– [BH(PzR1 R2 R3)(PzR2 R1 R3)2]– and [BH(PzR2 R1 R3)3]–are not referred to.

4. Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry

5. Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl)borate Ligands: Organometallic and Bioinorganic Perspectives

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