Polar Molecular Precursors for Alkali and Alkaline Earth Metal Clusters and Low‐Dimensional Polymer Structures: the Solid‐State Structures of [CaI(dme) 3 ]I, and cis ‐[SrI 2 (diglyme) 2 ] (dme = CH 3 OC 2 H 4 OCH 3 ; diglyme = CH 3 (OC 2 H 4 ) 2 OCH 3 )
Author:
Affiliation:
1. University of Karlsruhe, Institute for Inorganic Chemistry, Engesserstr., 76128 Karlsruhe, Germany
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200300241
Reference32 articles.
1. Structural Evolution from the Solid State to the Molecule for BaI2: Synthesis and Crystal Structures of[BaI2(μ2-OH2)2]3/∞,[BaI2(μ2-OH2)(OC3H6)]2/∞,[BaI2(thf)3]1/∞, and[BaI2(thf)5]· THF
2. Synthesis and crystal structure of Li[{Ca7(μ3-OH)8I6(thf)12}2(μ-I)]·3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol–gels
3. Similar Coordination - Different Dimensionality: Synthesis, Single Crystal Structures, and Theoretical Studies of Hydrogen-bonded {[Ca(H2O)2L4]I2}n/∞ (1: L = CH3COOC2H5, n = 1; 2: L = OC4H8, n = 2)
4. H-bonded polymer structures of different dimensionality: syntheses and crystal structures of [Ca(DME)n(H2O)m]I2·(DME)x (1: n=3, m=3, x=1; 2: n=2, m=4, x=0) and [Ca{CH3(OCH2)3OCH3}(H2O)4]I2
5. On the way to sol–gels: an analysis of the intra- and intermolecular hydrogen bonding in [Ba(OH)I(H2O)4]
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