Icosahedral Ga‐Centred Nickel Carbonyl Clusters: Synthesis and Characterization of [H 3– n Ni 12 (μ 12 ‐Ga)(CO) 22 ] n– ( n = 2, 3) and [Ni 14.3 (μ 12 ‐Ga)(CO) 24.3 ] 3

Icosahedral Ga‐Centred Nickel Carbonyl Clusters: Synthesis and Characterization of [H 3– n Ni 12 (μ 12 ‐Ga)(CO) 22 ] n– ( n = 2, 3) and [Ni 14.3 (μ 12 ‐Ga)(CO) 24.3 ] 3– Anions

Published:2010-02-22 Issue:7 Volume:2010 Page:1056-1062
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Femoni Cristina¹,Iapalucci Maria Carmela¹,Longoni Giuliano¹,Zacchini Stefano¹

Affiliation:

1. Dipartimento di Chimica Fisica ed Inorganica, Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy, Fax: +39‐0512093690

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200900904

Reference23 articles.

1. Synthesis, chromatographic separation, and stereophysical analysis of the homologous [Ni12-x(PMe)x(CO)24-3x]2- series (x = 2, 3, 4) containing noncentered Ni12-xPx icosahedral cages and the [Ni10(.mu.5-PMe)2(.mu.4-PMe)5(CO)10]2- dianion containing a structurally unprecedented heptacapped pentagonal prismatic metal cage: structural, spectroscopic, and electrochemical consequences due to replacement of Ni(CO)3 fragments with electronically equivalent (isolobal) PMe fragments

2. Synthesis and structural characterization of the [Ni9(AsPh)3(CO)15]2- and [Ni10(AsMe)2(CO)18]2- dianions containing noncentered icosahedral Ni12-xAsx cores (x = 2, 3): electronically equivalent metal cluster analogs of the regular icosahedral [B12H12]2- dianion

3. Reactions of the [Ni6(CO)12]2- dianion with stibine and bismuthine reagents: synthesis and stereophysical characterization of the [Ni10(SbPh)2(CO)18]2- dianion containing a noncentered icosahedral Ni10Sb2 core and Ni2(CO)4(μ2-Ph2SbOSbPh2)2 containing a centrosymmetric eight-membered (NiSbOSb)2 ring

4. New Nickel−Antimony Carbonyl Clusters: Stereochemical Analyses of the [Ni10(SbR)2(CO)18]2- Dianions (R = Me, Et, iPr, tBu, p-FC6H4) Containing Empty 1,12-Ni10Sb2 Icosahedral Cages and of the Unprecedented Stibinido-Bridged 34-Electron Ni2(CO)4(μ2-SbtBu2)2 Dimer1

5. A new family of metal-centred and noncentred icosahedral cages with transition metal and main group VI atoms: synthesis and structural-bonding analysis of the nickel-centred [Ni11Se2(CO)18]2–, nickel-centred [Ni10Te3(CO)15]2–and noncentred [Ni8Te4(CO)12]2–icosahedral dianions

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