Synthesis of the η 2 ‐1‐Phosphaallene Complexes [(η 5 ‐C 5 H 5 )(CO)(NO)W{η 2 ‐R 1 P=C=C(R 2 )H}] (R 1 = t Bu, Cy; R 2 = Ph, H) from [(η 5 ‐C 5 H 5 )(CO)(NO)W=C=C(R 2 )H] (R 2 = Ph, H) and Inversely Polarized Phosphaalkenes R 1 P=C(NMe 2 ) 2 (R 1 = t Bu, Cy), and Their Structure-Reference-Cited by-同舟云学术

Synthesis of the η 2 ‐1‐Phosphaallene Complexes [(η 5 ‐C 5 H 5 )(CO)(NO)W{η 2 ‐R 1 P=C=C(R 2 )H}] (R 1 = t Bu, Cy; R 2 = Ph, H) from [(η 5 ‐C 5 H 5 )(CO)(NO)W=C=C(R 2 )H] (R 2 = Ph, H) and Inversely Polarized Phosphaalkenes R 1 P=C(NMe 2 ) 2 (R 1 = t Bu, Cy), and Their Structure

Published:2007-01-22 Issue:4 Volume:2007 Page:562-567
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Weber Lothar¹,Noveski Gabriel¹,Braun Thomas¹,Stammler Hans‐Georg¹,Neumann Beate¹

Affiliation:

1. Fakultät für Chemie der Universität Bielefeld, Universitätsstrasse 25, 33615 Bielefeld, Germany, Fax: +49‐521‐106‐6146

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200600922

Reference21 articles.

1. Phosphaalkenes with Inverse Electron Density

2. A. W. Johnson) 1993 Wiley New York

3. Reaction of metal-carbene complexes with Wittig reagents. New vinyl ether synthesis

5. Reactivity of the Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R=tBu, Me3Si, H) towards Arylcarbene Complexes [(CO)5M=C(OEt)Ar] (Ar=Ph, M=Cr, W; Ar=2-MeC6H4, 2-MeOC6H4, M=W)

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