Synthesis and Solid State Structures of the Hydrogen‐Bonded Hexamolybdoplatinate(IV) Tetramer [(PtMo 6 O 24 ) 4 H 23 ] 9– and the Hexamolybdoplatinate(IV) Trimers [(PtMo 6 O 24 ) 3 H 16 ] 8– and [(PtMo 6 O 24 ) 3 H 14 ] 10

Synthesis and Solid State Structures of the Hydrogen‐Bonded Hexamolybdoplatinate(IV) Tetramer [(PtMo 6 O 24 ) 4 H 23 ] 9– and the Hexamolybdoplatinate(IV) Trimers [(PtMo 6 O 24 ) 3 H 16 ] 8– and [(PtMo 6 O 24 ) 3 H 14 ] 10–

Published:2009-11-17 Issue:34 Volume:2009 Page:5079-5087
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Day Victor W.¹,Goloboy James C.²,Klemperer Walter G.²

Affiliation:

1. Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045, USA

2. Department of Chemistry, University of Illinois at Urbana‐Champaign, 505 South Mathews Avenue, Urbana, IL 61801, USA

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200900873

Reference22 articles.

1. Prediction of PVT behavior of polymer melts by the group-contribution lattice-fluid equation of state

2. The K3.5[H4.5PtMo6O24]·3H2O structure (a) described in ref.[1]and the K3.5[H4.5PtMo6O24]·5.5H2O structure (b) described in ref.[3]appear to be virtually the same structure. Transformation of the nonstandard triclinic cell forato a standard triclinic cell gives the lattice constants 10.089Å × 12.001Å × 12.426Å × 69.25° × 69.27° × 83.44°; these closely resemble those reported forb. The transformed triclinic cell and the original triclinic cell forahave a volume of 1315.7Å3 not 1332.2 Å3as reported in ref.[3]. Metal–oxygen bond lengths inamatch those inbwithin two estimated standard deviations.

3. A. L. Spek PLATON: Program for the Geometrical Interpretation of Structural Data University of Utrecht 1999.

4. Estimate of a relationship between the number of atoms and the volumes of the unit cells of organic compounds

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