Lanthanide Borohydride Complexes of Bulky Guanidinate Ligands [(Me 3 Si) 2 NC(N‐Cy) 2 ] 2 Ln(μ‐BH 4 ) 2 Li(THF) 2 (Ln = Nd, Sm, Yb): Synthesis, Structure and Catalytic Activity in Lactide Polymerization-Reference-Cited by-同舟云学术

Lanthanide Borohydride Complexes of Bulky Guanidinate Ligands [(Me 3 Si) 2 NC(N‐Cy) 2 ] 2 Ln(μ‐BH 4 ) 2 Li(THF) 2 (Ln = Nd, Sm, Yb): Synthesis, Structure and Catalytic Activity in Lactide Polymerization

Published:2007-07 Issue:20 Volume:2007 Page:3260-3267
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Skvortsov Grigorii G.¹,Yakovenko Marina V.¹,Castro Pascal M.²,Fukin Georgy K.¹,Cherkasov Anton V.¹,Carpentier Jean‐François²,Trifonov Alexander A.¹

Affiliation:

1. G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina 49, 603950 Nizhny Novgorod GSP‐445, Russia, Fax: +7‐8312‐127‐497

2. Organometallics and Catalysis, UMR 6226, Institute of Chemistry, University of Rennes 1, 35042 Rennes Cedex, France

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200700123

Reference58 articles.

1. Organolanthanide tetrahydroborates. Ligation geometry and coordinative saturation

2. Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements

3. Unsolvated lanthanidocene hydrides and borohydrides. X-Ray crystal structure of [(η5-C5H3tBu2)2Ln(μ-H)]2 (Ln = Ce, Sm)

4. Crystal and molecular structures of bis(1,3-di-tert-butylcyclopentadienyl)cerium chloride and borohydride. First example of the bridging tetradentate BH4-group with two μ3-hydrogens: μ : η4-[(μ3-H)2B(μ2-H)2]

5. Metallocene(III) tetrahydridoborates of the Group 3Aelements and the X-ray structure of [Sc{η-C5H3(SiMe3)2}2(µ-H)2BH2]

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