Syntheses and Crystal Structures of Highly Diastereomerically Enriched Lithiated Benzylsilanes in the Presence of External Donor Molecules: Experiment and Theory-Reference-Cited by-同舟云学术

Syntheses and Crystal Structures of Highly Diastereomerically Enriched Lithiated Benzylsilanes in the Presence of External Donor Molecules: Experiment and Theory

Published:2003-09 Issue:18 Volume:2003 Page:3453-3463
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Strohmann Carsten¹,Buchold Daniel H. M.¹,Seibel Timo¹,Wild Kerstin¹,Schildbach Daniel¹

Affiliation:

1. Institut für Anorganische Chemie der Universität Würzburg Am Hubland, 97074 Würzburg, Germany, Fax: (internat.) +49‐(0)931/888‐4605

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200300323

Reference40 articles.

1. Remark: In general we speak ofenantiomerically enrichedmetal alkyls when we focus our interest on the stereogenic metallated carbon centre whereas these molecules are almost alwaysdiastereomerically enrichedmetal alkyls due to the presence of more stereogenic centres than only the metallated one.

3. Configurational Stability and Transfer of Stereochemical Information in the Reactions of Enantioenriched Organolithium Reagents

4. Enantioselective Synthesis with Lithium/(−)-Sparteine Carbanion Pairs

5. For examples see:

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