Preparation of GO‐SiO2 three‐dimensional point‐plane nanomaterials and enhancement of epoxy resin mechanical property

Author:

Hao Qiguo1,Zhang Xu1ORCID,Liu Shuang23,Peng Hongjun4,Zhang Pengyu5,Yu Shengyang4,Mao Zhiyi5

Affiliation:

1. Hebei Provincial Key Laboratory of Functional Polymers Hebei University of Technology Tianjin China

2. Academy of Low Carbon Concrete Beijing Building Materials Academy of Sciences Research Beijing China

3. Solid Waste Reuse for Building Materials State Key Laboratory Beijing Building Materials Academy of Sciences Research Beijing China

4. Technology Research and Development Department Dachang BBMG Coating Co. Ltd Langfang China

5. Research and Development Center Tianjin Building Materials Science Research Academy Co. Ltd. Tianjin China

Abstract

AbstractIn this research, mercapto‐anchoring graphene oxide (GO) and epoxy‐anchoring SiO2 nanoparticles (NPs) were assembled by mercapto‐epoxy click chemistry to form three‐dimensional (3D) point‐plane structure nanomaterials (GO‐SiO2), and epoxy resin (EP) composites were prepared using the auxiliary thermal blending method. The relationships among surface interfacial interaction, dispersion, and mechanical properties of composites were systematically investigated. The Research finding shows that SiO2 NPs covalently bonding with GO increases interface compatibility and dispersion, which explains epoxy composite strengthening. Compared to epoxy resin, 0.1 wt% GO‐SiO2/EP composite has 38.65%, 36.15%, 44.64%, and 61.61% higher tensile strength, flexural strength, flexural modulus, and impact strengths. The enhancement mechanism of GO‐SiO2 toward EP was analyzed.

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,General Chemistry,Ceramics and Composites

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