Mechanochemically‐Assisted Passerini Reactions: A Practical and Convenient Method for the Synthesis of Novel α‐Acyloxycarboxamide Derivatives

Author:

Salami Sodeeq Aderotimi1ORCID,Safari Justin Bazibuhe1ORCID,Smith Vincent J.1ORCID,Krause Rui W. M.1ORCID

Affiliation:

1. Center for Chemico- and Biomedicinal Research (CCBR) Rhodes University Grahamstown, Makhanda 6139 South Africa

Abstract

AbstractA carboxylic acid, an aldehyde, and an isonitrile were combined in a single step (Passerini reaction) under mechanochemical activation to produce several α‐acyloxycarboxamide derivatives in high to excellent yields within 15 min of milling. Mechanochemistry, when combined with the diversity provided by multicomponent reactions, enables the efficient synthesis of the target compounds, with great atom economy, shorter reaction times, and experimental simplicity. The method allows for the rapid production of a vast library of complex compounds from a limited number of substrates.

Funder

National Department of Health

Publisher

Wiley

Subject

General Chemistry

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