Ligand‐Promoted [Pd]‐Catalyzed α‐Alkylation of Ketones through a Borrowing‐Hydrogen Approach

Author:

Manojveer Seetharaman1ORCID,Garg Nitish K.1ORCID,Gul Zarif1,Kanwal Ayesha1,Goriya Yogesh1,Johnson Magnus T.12ORCID

Affiliation:

1. Centre for Analysis and Synthesis Department of Chemistry Lund University P. O. Box 124 221 00 Lund Sweden

2. Perstorp AB Perstorp Industrial Park 284 80 Perstorp Sweden

Abstract

AbstractA new class of palladium complexes bearing bidentate 2‐hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal‐ligand cooperative borrowing‐hydrogen (BH) process were demonstrated.

Funder

Vetenskapsrådet

Publisher

Wiley

Subject

General Chemistry

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