Affiliation:
1. School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 P. R. China
2. Department of Chemistry and Material Science College of Science Nanjing Forestry University Nanjing 210037 P. R. China
3. Xuzhou B&C Chemical Co., Ltd. Xuzhou 221300 P. R. China
Abstract
AbstractThis work for the first time reports that liquid metal (LM, gallium) behaves as a nucleating agent for the plastic poly(l‐lactide) (PLLA). The LM‐PLLA composites with different content (0–10%, by weight) of LM are fabricated by a twin crew extruder. The impacts of LM content on non‐isothermal and isothermal crystallization behavior are systematically investigated by calorimetry combing with Avrami's theory, determining an optimal LM content (2.5%) for advancing the crystallization of PLLA. Wide‐angle X‐ray diffraction (WAXD) shows that the excessive LM will interfere with the crystal structure of X%LM‐PLLA. As a kind of liquid state nucleating agent in plastic, the nucleation mechanism of LM for PLLA is attributed to the production of carboxylate ion clusters from the reaction between carboxylic acid on the end group of the PLLA chain and gallium, which is distinct from the epitaxy mechanism of previous solid nucleating agents.
Subject
Materials Chemistry,Organic Chemistry,Polymers and Plastics,Physical and Theoretical Chemistry,Condensed Matter Physics