Additive Effect of Graphene and Lignin‐Derived Graphene on Radical Polymerization Behaviors of Methacrylate Monomers-Reference-Cited by-同舟云学术

Additive Effect of Graphene and Lignin‐Derived Graphene on Radical Polymerization Behaviors of Methacrylate Monomers

Published:2023-10-28 Issue:23 Volume:224 Page:
ISSN:1022-1352
Container-title:Macromolecular Chemistry and Physics
language:en
Short-container-title:Macro Chemistry & Physics

Author:

Okamoto Shusuke¹,Fukuda Mami¹,Kawabata Koki¹,Komoda Ayumi²,Suwaki Ryo³,Mori Mikaru²,Fujishiro Fumito²,Ishii Takafumi⁴,Mori Masanobu²,Nagai Daisuke¹^ORCID

Affiliation:

1. School of Food and Nutritional Science University of Shizuoka 52‐1 Yada, Suruga‐ku Shizuoka 422‐8526 Japan

2. Graduate School of Science and Technology Kochi University 2‐5‐1 Akebono‐cho Kochi 780‐8520 Japan

3. Graduate School of TOSA Innovative Human Development Programs Kochi University 2‐5‐1 Akebono‐cho Kochi 780‐8520 Japan

4. International Research and Education Center for Element Science Faculty of Science and Technology Gunma University 1‐5‐1 Tenjin‐cho Kiryu Gunma 376‐8515 Japan

Abstract

AbstractRadical polymerizations of methyl methacrylate (MMA) using graphene or lignin‐derived graphene as additives give the corresponding poly(MMA)s of which much wider molecular weight distribution (MWD) than that of the poly(MMA) without additives. The MWD of the resulting poly(MMA) using graphene is wider compared to that using lignin‐derived graphene, suggesting that the structural differences between the two graphene compounds affect radical polymerization behavior. Furthermore, the radical polymerizations of methacrylate monomers with different substituents using the two graphene compounds are performed, leading to the additive effect of the two graphene compounds which is relevant to the steric hindrance of the monomer.

Publisher

Wiley

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics,Physical and Theoretical Chemistry,Condensed Matter Physics

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.202300276

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