Affiliation:
1. Key Laboratory of Polymer Processing Engineering Ministry of Education Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing South China University of Technology Guangzhou 510640 China
Abstract
AbstractThe blends of poly(butylene adipate‐co‐terephthalate) (PBAT), poly(propylene carbonate) (PPC), chain extender (ADR) and layered double hydroxides (LDH) are prepared by different extrusion methods. Effects of LDH and its distribution on rheology, phase morphology, mechanical properties, water vapor barrier properties and food preservation properties are investigated. Results show that when PBAT, PPC, and LDH are mixed directly, LDH is preferentially distributed in the PBAT phase. When LDH are mixed with PPC firstly and then further with PBAT, LDH mostly migrates to the interface of PBAT and PPC. The epoxy groups of ADR react with the terminal groups of the polymers to improve the interfacial compatibility. Adding LDH, the mechanical properties and barrier properties of the materials are improved and by premixing of PPC and LDH, properties of composites are further improved. Compared with PBAT/PPC blends, the tensile strength and elongation at break of PBAT/PPC(LDH‐0.5)/ADR increased by 25.2% and 15.3%, respectively. The banana packaged in PBAT/PPC/LDH films maintains good freshness. It illustrates that PBAT/PPC(LDH)/ADR composites have a good application prospect in the field of barrier and food packaging based on their excellent mechanical, barrier, and preservation properties.
Funder
Natural Science Foundation of Guangdong Province