Elastocaloric Effect and Magnetic Properties of Cu–Al–Mn Shape Memory Alloy

Author:

Zhao Shulei1,Li Chen1,Ma Guoliang1,Chen Mengru1,Yang Fengnan1,Zong Shuotong1,Zhang Yan1,Chen Fenghua12ORCID,Jiang Zhengyi2

Affiliation:

1. The Key Laboratory of Magnetic and Electric Functional Materials and Applications of Shanxi Province Taiyuan University of Science and Technology Taiyuan 030024 P. R. China

2. School of Mechanical, Materials, Mechatronic and Biomedical Engineering University of Wollongong Wollongong NSW 2522 Australia

Abstract

Herein, the magnetic properties and elastocaloric effects of Cu70Al19 + 0.5xMn11−0.5x (x = 0, 1, 2, 3) alloys are investigated. The resistance versus temperature curves indicate that the phase transition temperature increases as the Mn content decreases. In particular, the Cu70Al20.5Mn9.5 alloy exhibits a phase transition temperature close to room temperature. Therefore, the elastocaloric effects of this alloy are examined under stresses ranging from 200 to 500 MPa. The results show that the adiabatic temperature change of the alloy under a stress of 500 MPa reaches 9.8 K. Furthermore, the magnetization curves at 300 K reveal that the magnetic properties of the alloy significantly improve after undergoing low‐temperature aging treatment. The X‐ray diffraction patterns show that this improvement can be attributed to the transformation of the β1 phase to the ferromagnetic phase β3. Overall, the Cu70Al20.5Mn9.5 alloy demonstrates elastocaloric and magnetic properties comparable to those observed in certain Ni–Mn‐based alloys.

Funder

China Scholarship Council

Natural Science Foundation of Shanxi Province

Graduate Research and Innovation Projects of Jiangsu Province

Publisher

Wiley

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics,Electronic, Optical and Magnetic Materials

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