Giant Ferroelectric and Piezoelectric Properties of Lead Free Ba0.85Ca0.15Ti0.90Zr0.10O3 Thin Film in 100 nm Thickness Range

Author:

Dai Qingping12ORCID,Li Yumin1,Wei Jun1,Li Qiongmin1,Qiu Zhibin1,Pu Yuanmao1

Affiliation:

1. Key Laboratory of Low Dimensional Condensed Matter Physics of Higher Educational Institution of Guizhou Province School of Physics and Electronic Science Guizhou Normal University Guiyang 550001 China

2. School of Science Minzu University of China Beijing 100081 China

Abstract

Lead‐free Ba0.85Ca0.15Ti0.90Zr0.10O3/SrRuO3 (BCZT/SRO)‐heterostructured thin film grown on (001)‐SrTiO3 substrate is prepared by pulse laser deposition. The microstructure, ferroelectric, and piezoelectric of the thin film are investigated in detail. Giant ferroelectric properties of the BCZT thin films with thickness ≈100 nm and remanent polarization Pr of 57.1 μC cm−2 are obtained, which are attributed to the (00L)‐oriented epitaxial structure and lower substrate clamping. In addition, the BCZT/SRO heterostructure exhibits excellent piezoelectric properties with the d33 values of different grain size (40–140 nm) varied from 75 to 130 pm V−1, providing a potential candidate used as piezoelectric material for magnetoelectric composite films. The BCZT/SRO‐heterostructured thin film with excellent ferroelectric and piezoelectric properties may be a good alternative to Pb(ZrxTi1−x)O3 thin films for piezoelectric device applications.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics,Electronic, Optical and Magnetic Materials

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. High macroscopic piezoelectric d33 of the nm-thick flexible PZT ferroelectric film;Journal of Materials Science: Materials in Electronics;2024-02

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