Initial Photocarrier Generation Process in Organic Photovoltaics Observed with Light‐Triggered Time‐Domain Reflectometry

Author:

Mashiko Tomoaki1,Takano Koki1,Kaino Akira1,Kuromasa Sou1,Fujii Shintaro1,Omori Tatsuya1,Sakai Masatoshi1ORCID,Kudo Kazuhiro1,Mino Hirofumi2

Affiliation:

1. Department of Electrical and Electronic Engineering Chiba University Chiba City 263-8522 Japan

2. Graduate School of Global and Transdisciplinary Studies Chiba University Chiba City 263-8522 Japan

Abstract

Herein, a time‐resolved electrical measurement is developed to observe the transient impedance of organic photovoltaics (OPV) and traced the initial photocarrier generation dynamics with the time region from 10 ns to 190 μs. A light‐triggered time‐domain reflectometry is adopted to observe the initial carrier dynamics in OPV by synchronizing rectangular light pulses from LED with a transient impedance probe pulse. Both the rising and recovery processes of OPV are observed in detail. The time evolution of the photocarrier distribution is calculated based on the diffusion–recombination scheme and is discussed in the initial process of photocarrier generation.

Funder

Murata Science Foundation

Publisher

Wiley

Subject

Materials Chemistry,Electrical and Electronic Engineering,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics,Electronic, Optical and Magnetic Materials

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