Affiliation:
1. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology Beijing 100190 P. R. China
2. University of Chinese Academy of Sciences Beijing 100049 P. R. China
Abstract
As a roll‐to‐roll compatible technology, slot‐die coating has shown great potential for manufacturing industrial‐level organic solar cells (OSCs). However, in the slot‐die coatings process, coffee rings are often formed due to the slow film‐forming kinetics, leading to a significant loss of power conversion efficiency (PCE) in upscaling device area. Herein, the coffee rings are suppressed by introducing an airflow‐assisted slot‐die technique to obtain a suitable active layer morphology with improved flatness and homogeneity. Synergistically, optimization of airflow and substrate temperature conditions, the PCE of 1 cm2 flexible OSC devices reaches 13.69%. Moreover, large‐area flexible OSC modules with 30 cm2 achieve a PCE of 13.08%, maintaining 95% of 1 cm2 device, which is the minimum PCE loss from 1 cm2 to large‐area devices. Morphology characterization shows that airflow can suppress excessive molecular aggregation and obtain suitable phase separation. Therefore, this work provides an efficient method to fabricate high‐efficiency flexible large‐area OSC modules, which will promote OSC devices from lab to fab.
Funder
National Natural Science Foundation of China
Subject
Electrical and Electronic Engineering,Energy Engineering and Power Technology,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials