Affiliation:
1. School of Chemistry and Chemical Engineering Hefei University of Technology Hefei Anhui 230009 P. R. China
2. College of Science Shijiazhuang University Shijiazhuang Hebei 050035 P. R. China
3. College of Physics Hebei Advanced Thin Films Laboratory Hebei Normal University Shijiazhuang Hebei 050024 P. R. China
Abstract
Modification of hole transporting layers (HTLs) to reduce the interface defects is an important strategy to promote hole extraction and suppress charge recombination for Sb2(S,Se)3 (antimony selenosulfide) solar cells. Herein, a simple doping method with the tetrathiafulvalene derivatives (MeS‐TTF and Cyano‐TTF) is developed to reduce the dangling bonding defects on the surface of Sb2(S,Se)3 films and improve the photovoltaic performances of Sb2(S,Se)3 solar cells. The studies show that the tetrathiafulvalene derivatives can effectively passivate the ionic defects through the chelation mechanism with Sb atoms and suppress the nonradiative recombination. Meanwhile, the MeS‐TTF dopant can also enhance the hole mobility of HTLs and improve the hole transport. The results indicate that the MeS‐TTF can achieve the dual function of interface defect passivation and hole mobility improvement. As a result of the dual‐function dopant, a significant increase in efficiency from 7.73% to 8.45% can be obtained. The outcomes of this study highlight that this dual‐function doping strategy is an effective method to passivate the interface defects and enhance the hole mobility for the excellent photovoltaic performances of Sb2(S,Se)3 solar cells.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Anhui Province
Subject
Electrical and Electronic Engineering,Energy Engineering and Power Technology,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials
Cited by
2 articles.
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