Affiliation:
1. Institute of Nanoscience, Nanotechnology and Molecular Materials (INAMOL) Universidad de Castilla-La Mancha Campus de la Fábrica de Armas 45071 Toledo Spain
2. Department of Physics The LNM Institute of Information Technology (Deemed University) Jamdoli Jaipur (Raj.) 302031 India
3. Department of Physics Malviya National Institute of Information Technology JLN Marg Jaipur (Raj.) 302017 India
Abstract
Ternary architecture is a promising strategy to achieve high efficiency in organic solar cells. The alignment of third‐component frontier orbitals with those of donor and acceptor (D and A) is of essential importance. Herein, a new molecule VC11, consisting of a Cu(II)–porphyrin core linked to dicyanovinylene terminal acceptor units through (E)‐1,2‐di(thiophen‐2‐yl) ethene bridges, is described. The highest occupied molecular orbital and lowest unoccupied molecular orbital values of VC11 are −5.52 and −3.74 eV, respectively, lying between the corresponding values of PBDB‐T donor and Y6 acceptor, compounds used in the construction of the studied devices. The measured electron and hole mobilities reveal similar values, in the order of 10−4 cm2 Vs−1, indicating the ambipolarity of VC11, that can be used as donor or acceptor. The organic solar cells (OSCs) based on PBDB‐T:VC11, VC11:Y6, and PBDB‐T:Y6 show power conversion efficiencies (PCEs) of 10.84%, 7.89%, and 11.98%, respectively. VC11 is utilized along with PBDB‐T and Y6 to form a ternary active layer for assembling bulk heterojunction OSCs affording a remarkable PCE of 15.25%, significantly higher than those obtained for the corresponding binary devices. This enhancement of PCE originates from the additional charge separation offered by a cascaded energy‐level alignment and a fast charge transfer, due the ambipolarity of VC11.
Funder
Ministerio de Ciencia e Innovación
Spanish National Plan for Scientific and Technical Research and Innovation
Junta de Comunidades de Castilla-La Mancha
Ministerio de Educación, Cultura y Deporte
Subject
Electrical and Electronic Engineering,Energy Engineering and Power Technology,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials
Cited by
4 articles.
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