Affiliation:
1. Guangzhou Key Laboratory of Vacuum Coating Technologies and New Energy Materials Siyuan Laboratory Department of Physics Jinan University Guangzhou 510632 P. R. China
2. Shanghai Synchrotron Radiation Facility (SSRF) Zhangjiang Lab Shanghai Advanced Research Institute Chinese Academy of Sciences Shanghai 201204 P. R. China
3. School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
4. State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices South China University of Technology Guangzhou 510640 P. R. China
Abstract
The 2D Ruddlesden–Popper perovskites (RPPs), consisting of alternating organic spacer layers and inorganic layers, are emerging photovoltaic materials because of their highly tunable optoelectronic properties and improved stability compared to their 3D counterparts. Nonhalide lead sources attract increasing attention in 3D perovskites, whereas the lead sources for RPPs are limited to lead halides. Herein, nonhalide lead source of lead acetate is investigated for high‐quality RPP films by a dimethyl sulfoxide (DMSO)‐assisted delayed annealing process. The incorporation of DMSO in the lead acetate–based precursor solution regulates the crystallization process, resulting in RPP films with distinctly enhanced crystallinity, reduced trap density, vertical crystal orientation, and graded phase distribution. Consequently, the optimized RPP solar cell with an inverted planar structure delivers a champion power conversion efficiency of 17.3%. Herein, future developments of nonhalide lead sources are spurred to fabricate RPP films with high device performance.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Basic and Applied Basic Research Foundation of Guangdong Province
National Key Research and Development Program of China
Subject
Electrical and Electronic Engineering,Energy Engineering and Power Technology,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials
Cited by
2 articles.
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