Group additive kinetic modeling for carbon-centered radical addition to oxygenates and β-scission of oxygenates

Author:

Paraskevas Paschalis D.12,Sabbe Maarten K.1,Reyniers Marie-Françoise1,Marin Guy B.1,Papayannakos Nikos G.3

Affiliation:

1. Laboratorium voor Chemische Technologie; Universiteit Gent; Technologiepark 914 9052 Gent Belgium

2. School of Chemical Engineering; National Technical University of Athens; 15780 Athens Greece

3. School of Chemical Engineering, National Technical University of Athens; 15780 Athens Greece

Funder

European Research Council

European Union's Seventh Framework Program

Long Term Structural Methusalem Funding

Flemish Government

Scientific Research-Flanders (F.W.O.-Vlaanderen)

Publisher

Wiley

Subject

General Chemical Engineering,Environmental Engineering,Biotechnology

Reference53 articles.

1. Further considerations on the thermodynamics of chemical equilibria and reaction rates;Evans;Proc R Soc A,1936

2. Inertia and driving force of chemical reactions;Evans;Trans Faraday Soc,1938

3. New empirical models of free radical abstraction reactions;Denisov;Usp Khim+,1997

4. Engineering approximations for activation energies in hydrogen transfer reactions;Blowers;AIChE J,2000

5. Factors controlling the addition of carbon-centered radicals to alkenes-an experimental and theoretical perspective;Fischer;Angew Chem-Int Ed Engl,2001

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