Efficient removal of Pb(II) and Cd(II) ions from wastewater using amidoxime functionalized graphene oxide

Author:

Zou Lin1,Shang Wan1,Min Tingting1,Zhang Biyu1,Yuan Lu1234,Peng Xin1234,Chen Xiangping1234

Affiliation:

1. College of Chemistry and Chemical Engineering Hunan Normal University Changsha People's Republic of China

2. National & Local Joint Engineering Laboratory for New Petro‐chemical Materials and Fine Utilization of Resources Changsha People's Republic of China

3. Key Laboratory of Sustainable Resources Processing and Advanced Materials of Hunan Province College Changsha People's Republic of China

4. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Hunan Normal University), Ministry of Education Changsha People's Republic of China

Abstract

AbstractThis study aimed to develop iminodiethylamine oxime graphite oxide (IOGO) through the grafting of iminodiethylamine oxime onto graphene oxide (GO) via amidation and oximation. The primary objective was to investigate the adsorption characteristics of Pb(II) and Cd(II) ions on IOGO. Results demonstrated that IOGO exhibited exceptional adsorption capabilities, reaching maximum adsorption capacities of 798.87 mg/g for Pb(II) and 283.50 mg/g for Cd(II). Remarkably, IOGO maintained its high adsorption performance over five consecutive adsorption cycles. Specifically, the adsorption capacity for Pb(II) remained significantly stable at 480.78 mg/g, exhibiting only an 8.77% decrease. Similarly, the Cd(II) adsorption capacity remained robust at 204.13 mg/g, demonstrating a modest reduction of 10.47%. These findings underscore the feasibility of employing IOGO in repeated adsorption processes, thereby showcasing its potential for practical applications in the removal of heavy metals from aqueous solutions.

Publisher

Wiley

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