Affiliation:
1. Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology School of Physics Science and Engineering Tongji University Shanghai 200092 P. R. China
Abstract
AbstractElectrochromic devices have important applications in building energy conservation, next‐generation displaying, and security encryption, while durable and high‐performance electrochromic materials are highly desirable. Herein, a Zn‐based electrochromic smart window by using 3D ordered macroporous amorphous WO3 (a‐WO3) arrays as cathode is reported. Benefiting from a 3D ordered macroporous structure with a high specific surface area that accelerates the ion diffusion and migration, and the oxygen vacancy modulated a‐WO3 providing abundant zinc ion insertion channels, the as‐fabricated zinc‐based a‐WO3 inverse opal (a‐WO3‐IO) device exhibits excellent electrochromic properties, including large light modulation (83% optical contrast at 700 nm), fast response time (5.3 s for coloring and 3.2 s for bleaching), and robust cycling stability. Moreover, a solid‐state a‐WO3‐IO prototype electrochromic smart window is demonstrated for light modulation, electronic display, and power supply. Furthermore, experimental results and theoretical calculations reveal that 3D macroporous amorphous WO3 with rich oxygen vacancies can enhance the zinc ion absorption and diffusion, leading to the enhancement of electrochromic performance.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Subject
Industrial and Manufacturing Engineering,Mechanics of Materials,General Materials Science