Affiliation:
1. Department of Chemical and Metallurgical Engineering Aalto University Kemistintie 1 Espoo FI‐00076 Finland
2. College of New Energy Ningbo University of Technology Ningbo 315336 China
3. Advanced Institute for Materials Research Tohoku University Katahira, Aoba‐ku Sendai 980‐8577 Japan
4. State Key Laboratory of Chemical Engineering Tianjin Key Laboratory of Applied Catalysis Science and Technology School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China
Abstract
AbstractA lithium oxygen battery (LOB) with molten salt electrolyte operating at elevated temperature has aroused great interest because it enables fast reaction kinetics. However, there is still a lack of open literature on the separator (membrane) of this kind of LOB. Metal‐organic framework (MOF) materials are widely used as components of separators in many kinds of energy storage devices, due to their regular crystalline and well‐defined pore structures. In this work, a MOF material, zirconium (II) 1,4‐benzenedicarboxylate after lithiation (UiO‐66‐SO3Li) with a narrow pore size (6 Å), is used as a key component of the separator for LOB operating at elevated temperature. A “rolling dough” method is adopted to prepare the separator, which achieves 100% material utilization. The LOB with this membrane operates at 160 °C and delivers a specific capacity of 5.1 mAh cm−2 with an overpotential as low as 40 mV at 0.1 mA cm−2 and a prolonged cycle life, 180 cycles with a high coulombic efficiency of 99.9% at 0.5 mA cm−2. This MOF‐based membrane provides efficient Li+ transfer and restricts discharge product migration during battery operation, which is promising for the development of LOB in large‐scale practical applications.
Funder
Academy of Finland
Aalto-yliopisto
China Scholarship Council
Subject
Industrial and Manufacturing Engineering,Mechanics of Materials,General Materials Science
Cited by
2 articles.
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