Affiliation:
1. School of Materials Science and Engineering Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials Shaanxi University of Science and Technology Xi'an 710021 P. R. China
2. State Key Laboratory of Power System Operation and Control Department of Electrical Engineering Tsinghua University Beijing 100084 P. R. China
3. Key Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin 150080 P. R. China
Abstract
AbstractIn this work, a distinctive “metal‐ion organic hybrid interface” (MOHI) between polyimide (PI) and calcium niobate (CNO) nanosheets is designed. The metal ions in the MOHI can achieve atomic‐level matching not only with the inorganic CNO, but also with the PI chains, forming uniform and strong chemical bonds. These results are demonstrated by experiment and theory calculations. Significantly, the MOHI reduces the free volume and introduces deep traps across the filler‐matrix interfacial area, thus suppressing the electric field distortion in PI‐based composite dielectrics. Consequently, PI‐based dielectric containing the MOHI exhibits excellent energy storage performance. The energy storage densities (Ue) of the composite dielectric reach 9.42 J cm−3 and 4.75 J cm−3 with energy storage efficiency (η) of 90% at 25 °C and 150 °C respectively, which are 2.6 and 11.6 times higher than those of pure PI. This study provides new ideas for polymer‐based composite dielectrics in high energy storage.
Funder
National Natural Science Foundation of China
China Postdoctoral Science Foundation
Natural Science Basic Research Program of Shaanxi Province
Cited by
6 articles.
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