Synergetic Enhancement of Strength–Ductility and Thermoelectric Properties of Ag2Te by Domain Boundaries

Author:

Wang Hongtao1,Feng Xiaobin1,Lu Zhongtao1,Duan Bo1,Yang Houjiang1,Wu Luoqi1,Zhou Ling1,Zhai Pengcheng12,Snyder G. Jeffrey3,Li Guodong12ORCID,Zhang Qingjie2

Affiliation:

1. Hubei Key Laboratory of Theory and Application of Advanced Materials Mechanics Wuhan University of Technology Wuhan 430070 China

2. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China

3. Department of Materials Science and Engineering Northwestern University Evanston IL 60208 USA

Abstract

AbstractSimultaneously improving the mechanical and thermoelectric (TE) properties is significant for the engineering applications of inorganic TE materials. In this work, a novel nanodomain strategy is developed for Ag2Te compounds to yield 40% and 200% improved compressive strength (160 MPa) and fracture strain (16%) when compared to domain‐free samples (115 MPa and 5.5%, respectively). The domained samples also achieve a 45% improvement in average ZT value. The domain boundaries (DBs) provide extra sites for dislocation nucleation while pinning the dislocation movement, resulting in superior strength and ductility. In addition, phonon scattering induced by DBs suppresses the lattice thermal conductivity of Ag2Te and also reduces the weighted mobility. These findings provide new insights into grain and DB engineering for high‐performance inorganic semiconductors with robust mechanical properties.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

U.S. Department of Commerce

National Institute of Standards and Technology

Publisher

Wiley

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

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