Exciton Dissociation and Recombination Afford Narrowband Organic Afterglow Through Efficient FRET

Author:

Zhang Jingyu1,Wang Wuji1,Bian Yanfang1,Wang Yike1,Lu Xinchi1,Guo Zhenli1,Sun Chengxi1,Li Zecai1,Zhang Xiao1,Yuan Jie12,Tao Ye1,Huang Wei13,Chen Runfeng1ORCID

Affiliation:

1. State Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM) Nanjing University of Posts and Telecommunications 9 Wenyuan Road Nanjing 210023 China

2. Nanjing Vocational University of Industry Technology 1 Yangshan North Road Nanjing 210023 China

3. Frontiers Science Center for Flexible Electronics (FSCFE) MIIT Key Laboratory of Flexible Electronics (KLoFE) Shaanxi Key Laboratory of Flexible Electronics Xi'an Key Laboratory of Flexible Electronics Xi'an Key Laboratory of Biomedical Materials & Engineering Xi'an Institute of Flexible Electronics Institute of Flexible Electronics (IFE) Northwestern Polytechnical University Xi'an Shanxi 710072 China

Abstract

AbstractOrganic afterglow with long‐persistent luminescence (LPL) after photoexcitation is highly attractive, but the realization of narrowband afterglow with small full‐width at half‐maximum (FWHM) is a huge challenge since it is intrinsically contradictory to the triplet‐ and solid‐state emission nature of organic afterglow. Here, narrow‐band, long‐lived, and full‐color organic LPL is realized by isolating multi‐resonant thermally activated delayed fluorescent (MR‐TADF) fluorophores in a glassy steroid‐type host through a facile melt‐cooling treatment. Such prepared host becomes capable of exciton dissociation and recombination (EDR) upon photoirradiation for both long‐lived fluorescence and phosphorescence; and, the efficient Förster resonance energy transfer (FRET) from the host to various MR‐TADF emitters leads to high‐performance LPL, exhibiting small FWHM of 33 nm, long persistent time over 10 s, and facile color‐tuning in a wide range from deep‐blue to orange (414–600 nm). Moreover, with the extraordinary narrowband LPL and easy processability of the material, centimeter‐scale flexible optical waveguide fibers and integrated FWHM/color/lifetime‐resolved multilevel encryption/decryption devices have been designed and fabricated. This novel EDR and singlet/triplet‐to‐singlet FRET strategy to achieve excellent LPL performances illustrates a promising way for constructing flexible organic afterglow with easy preparation methods, shedding valuable scientific insights into the design of narrow‐band emission in organic afterglow.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Wiley

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