Revitalizing Oxygen Reduction Reactivity of Composite Oxide Electrodes via Electrochemically Deposited PrOx Nanocatalysts

Author:

Nam Seongwoo1,Kim Jinwook1,Kim Hyunseung1,Ahn Sejong1,Jeon SungHyun1,Choi Yoonseok2,Park Beom‐Kyeong3,Jung WooChul1ORCID

Affiliation:

1. Department of Materials Science and Engineering Korea Advanced Insititute of Science and Technology (KAIST) 291 Daehak‐ro Yuseong‐gu Daejeon 34141 Republic of Korea

2. Hydrogen Convergence Materials Laboratory Korea Institute of Energy Research (KIER) Gajeong‐ro, Yuseong‐gu Daejeon 34129 Republic of Korea

3. School of Materials Science and Engineering Pusan National University 2, Busandaehak‐ro‐63‐beon‐gil, Geumjeong‐gu Busan 46241 Republic of Korea

Abstract

AbstractSolid oxide fuel cells that operate at intermediate temperatures require efficient catalysts to enhance the inherently poor electrochemical activity of the composite electrodes. Here, a simple and practical electrochemical deposition method is presented for fabricating a PrOx overlayer on lanthanum strontium manganite–yttria‐stabilized zirconia (LSM–YSZ) composite electrodes. The method requires less than four minutes for completion and can be carried out under at ambient temperature and pressure. Crucially, the treatment significantly improves the electrode's performance without requiring heat treatment or other supplementary processes. The PrOx‐coated LSM–YSZ electrode exhibits an 89% decrease in polarization resistance at 650 °C (compared to an untreated electrode), maintaining a tenfold reduction after ≈400 h. Transmission line model analysis using impedance spectra confirms how PrOx coating improved the oxygen reduction reaction activity. Further, tests with anode‐supported single cells reveal an outstanding peak power density compared to those of other LSM–YSZ‐based cathodes (e.g., 418 mW cm−2 at 650 °C). Furthermore, it is demonstrated that multicomponent coating, such as (Pr,Ce)Ox, can also be obtained with this method. Overall, the observations offer a promising route for the development of high‐performance solid oxide fuel cells.

Funder

National Research Foundation of Korea

Korea Institute of Energy Technology Evaluation and Planning

Korea Research Institute of Chemical Technology

Publisher

Wiley

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