Affiliation:
1. Research Center of Grid Energy Storage and Battery Application School of Electrical Engineering Zhengzhou University Zhengzhou 450001 China
2. Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 China
3. Centre for Clean Energy Technology School of Mathematical and Physical Sciences Faculty of Science University of Technology Sydney Ultimo New South Wales 2007 Australia
4. Centre for Cooperative Research on Alternative Energies (CIC energiGUNE) Basque Research and Technology Alliance (BRTA) Alava Technology Park, Albert Einstein 48 Vitoria‐Gasteiz 01510 Spain
Abstract
AbstractAqueous Zn metal batteries are considered as competitive candidates for next‐generation energy storage systems due to their excellent safety, low cost, and environmental friendliness. However, the inevitable dendrite growth, severe hydrogen evolution, surface passivation, and sluggish reaction kinetics of Zn metal anodes hinder the practical application of Zn metal batteries. Detailed summaries and prospects have been reported focusing on the research progress and challenges of Zn metal anodes, including electrolyte engineering, electrode structure design, and surface modification. However, the essential electrical mechanisms that significantly influence Zn2+ ions migration and deposition behaviors have not been reviewed yet. Herein, in this review, the regulation mechanisms of electrical‐related electrostatic repulsive/attractive interactions on Zn2+ ions migration, desolvation, and deposition behaviors are systematically discussed. Meanwhile, electric field regulation strategies to promote the Zn2+ ions diffusion and uniform Zn deposition are comprehensively reviewed, including enhancing and homogenizing electric field intensity inside the batteries and adding external magnetic/pressure/thermal field to couple with the electric field. Finally, future perspectives on the research directions of the electrical‐related strategies for building better Zn metal batteries in practical applications are offered.
Funder
Australian Research Council
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science