Affiliation:
1. Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials College of Physics and Energy Fujian Normal University Fuzhou 350117 P. R. China
2. Fujian Provincial Collaborative Innovation Center for Advanced High‐Field Superconducting Materials and Engineering Fuzhou 350117 P. R. China
3. State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences (CAS) Fuzhou 350117 P. R. China
4. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108 P. R. China
Abstract
AbstractSolar interfacial water evaporation shows great potential to address the global freshwater scarcity. Water evaporation being inherently energy intensive, Joule‐heating assisted solar evaporation for addressing insufficient vapor under natural conditions is an ideal strategy. However, the simultaneous optimization of low evaporation enthalpy, high photothermal conversion, and excellent Joule‐heating steam generation within a single material remain a rare achievement. Herein, inspired by the biological channel structures, a large‐area film with hierarchical macro/microporous structures is elaborately designed by stacking the nanosheet of a conductive metal–organic framework (MOF), Ni3(HITP)2, on a paper substrate. By combining the above three features in one material, the water evaporation enthalpy reduces from 2455 J g−1 to 1676 J g−1, and the photothermal conversion efficiency increases from 13.75% to 96.25%. Benefiting from the synergistic photothermal and Joule‐heating effects, the evaporation rate achieves 2.60 kg m−2 h−1 under one sun plus input electrical power of 4 W, surpassing the thermodynamic limit and marking the highest reported value in MOF‐based evaporators. Moreover, Ni3(HITP)2‐paper exhibits excellent long‐term stability in simulated seawater, where no salt crystallization and evaporation rate degradation are observed. This design strategy for nanosheet films with hierarchical macro/microporous channels provides inspiration for electronics, biological devices, and energy applications.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Fujian Province
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science