Lattice‐Gradient Perovskite KTaO3 Films for an Ultrastable and Low‐Dose X‐Ray Detector

Abstract

AbstractConventional indirect X‐ray detectors employ scintillating phosphors to convert X‐ray photons into photodiode‐detectable visible photons, leading to low conversion efficiencies, low spatial resolutions, and optical crosstalk. Consequently, X‐ray detectors that directly convert photons into electric signals have long been desired for high‐performance medical imaging and industrial inspection. Although emerging hybrid inorganic–organic halide perovskites, such as CH3NH3PbI3 and CH3NH3PbBr3, exhibit high sensitivity, they have salient drawbacks including structural instability, ion motion, and the use of toxic Pb. Here, this work reports an ultrastable, low‐dose X‐ray detector comprising KTaO3 perovskite films epitaxially grown on a Nb‐doped strontium titanate substrate using a low‐cost solution method. The detector exhibits a stable photocurrent under high‐dose irradiation, high‐temperature (200 °C), and aqueous conditions. Moreover, the prototype KTaO3‐film‐based detector exhibits a 150‐fold higher sensitivity (3150 µC Gyair−1cm−2) and 150‐fold lower detection limit (<40 nGyair s−1) than those of commercial α‐Se‐based direct detectors. Systematic investigations reveal that the high stability of the detector originates from the strong covalent bonds within the KTaO3 film, whereas the low detection limit is due to a lattice‐gradient‐driven built‐in electric field and the high insulating property of KTaO3 film. This study unveils a new path toward the fabrication of green, stable, and low‐dose X‐ray detectors using oxide perovskite films, which have significant application potential in medical imaging and security operations.