Engineering the Intrinsic Chirality of Plasmonic Au@Pd Metamaterials for Highly Sensitive Chiroplasmonic Hydrogen Sensing

Abstract

AbstractMetal helicoid nanoparticles with intrinsic 3D chiral structures have emerged as a new class of plasmonic metamaterials with outstanding chiroplasmonic properties. Despite the considerable potential of metal helicoid nanoparticles in chiroplasmonic sensing, their sensing capabilities remain elusive, stressing the need for the rational chirality engineering of helicoid nanoparticles. In this report, Au@Pd helicoid nanoparticles with engineered chiroplasmonic properties and integrated hydrogen sensing capabilities are rationally synthesized. As chiroplasmonic metamaterials, the Au@Pd helicoid nanoparticles exhibit unprecedented sensitivity for hydrogen chiroplasmonic sensing in the visible range. A significant circular dichroism red‐shift as large as 206.1 nm can be achieved when they are exposed to hydrogen. Such a high sensitivity outperforms all the plasmonic hydrogen sensors in the visible range. Besides sensitivity, the chiroplasmonic sensing platform shows a good linear range of 1.5–6.0% hydrogen concentration with higher figure of merit, excellent selectivity, and good reusability. To further demonstrate its applicability, this chiroplasmonic hydrogen sensing platform is utilized to investigate hydrogen absorption and desorption kinetics on Pd. This study heralds a new paradigm for plasmonic hydrogen sensing and highlights the tremendous potential of utilizing helicoid nanoparticles as chiroplasmonic sensing metamaterials by chirality engineering.