Affiliation:
1. Center for Organic Photonics and Electronics Research (OPERA) Kyushu University 744 Motooka, Nishi Fukuoka 819‐0395 Japan
2. International Institute for Carbon Neutral Energy Research (WPI‐I2CNER) Kyushu University 744 Motooka, Nishi Fukuoka 819‐0395 Japan
Abstract
AbstractRecently, there has been intense interest in pure organic room‐temperature phosphorescence (ORTP) from cocrystals composed of 1,4‐diiodotetrafluorobenzene (DITFB) and a variety of polycyclic aromatic hydrocarbons (PAHs) or their derivatives. To expand the possibility of halogen bonding‐based cocrystals, the relationship between the crystal packing motifs and ORTP characteristics in binary cocrystals composed of DITFB and PAHs of phenanthrene (Phen), chrysene (Chry), and pyrene (Pyr), respectively, is investigated. The σ‐hole···π and π‐hole···π interactions determine not only the crystal packing motifs but also photoluminescence quantum yields (PLQYs). The Phen‐DITFB and Chry‐DITFB binary cocrystals with σ‐hole···π interactions show higher PLQY compared with the Pyr‐DITFB binary cocrystal with π‐hole···π interaction. Further, to clarify the effect of crystal structures on PLQY, ternary cocrystals are prepared by partially doping Pyr into Phen‐DITFB. The crystal packing motif of the ternary cocrystal originates from a Phen‐DITFB cocrystal with σ‐hole···π interaction, and some of the Phen sites are randomly replaced with Pyr molecules. The ORTP emission is derived from Pyr. The maximum PLQY is >20% due to suppressing nonradiative decay by changing the crystal packing motif.
Funder
Japan Science and Technology Agency
Core Research for Evolutional Science and Technology
Subject
Mechanical Engineering,Mechanics of Materials,General Materials Science
Cited by
14 articles.
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