Ultrastable Electrolytic Zn–I2 Batteries Based on Nanocarbon Wrapped by Highly Efficient Single‐Atom Fe‐NC Iodine Catalysts

Author:

Wang Yueyang1,Jin Xiangrong1,Xiong Jiawei2,Zhu Qingyi1,Li Qi1,Wang Runze1,Li Jiazhan1,Fan Yanchen3,Zhao Yi145,Sun Xiaoming1ORCID

Affiliation:

1. State Key Laboratory of Chemical Engineering College of Chemistry Beijing University of Chemical Technology Beijing 100029 China

2. Mary Frances Early College of Education The University of Georgia Athens GA 30602 USA

3. PetroChina Shenzhen New Energy Research Institute Shenzhen 518000 China

4. Advanced Technology Research Institute Beijing Institute of Technology Jinan 250300 China

5. Collaborative Innovation Center of Electric Vehicles in Beijing Beijing 100081 China

Abstract

AbstractAqueous Zn–iodine (Zn–I2) conversion batteries with iodine redox chemistry suffers the severe polyiodide shuttling and sluggish redox kinetics, which impede the battery lifespan and rate capability. Herein, an ultrastable Zn–I2 battery is introduced based on single‐atom Fe–N–C encapsulated high‐surface‐area carbon (HC@FeNC) as the core–shell cathode materials, which accelerate the I/I3/I° conversion significantly. The robust chemical–physical interaction between polyiodides and Fe–N4 sites tightly binds the polyiodide ions and suppresses the polyiodide shuttling, thereby significantly enhancing the coulombic efficiency. As a result, the core–shell HC@FeNC cathode endows the electrolytic Zn–I2 battery with an excellent capacity, remarkable rate capability, and an ultralong lifespan over 60 000 cycles. More importantly, a practical 253 Wh kg−1 pouch cell shows good capacity retention of 84% after 100 cycles, underscoring its considerable potential for commercial Zn–I2 batteries.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Beijing Municipality

Publisher

Wiley

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