Mechanisms and regioselectivities of DABCO/DMAP‐catalyzed [2+4] annulation reactions of allenoate with α,β‐unsaturated cyclic ketimine: A DFT study
Author:
Affiliation:
1. Department of Pathophysiology, School of Basic Medical SciencesZhengzhou University Zhengzhou China
Funder
National Natural Science Foundation of China
Publisher
Wiley
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/poc.3914
Reference42 articles.
1. Enantioselective catalysis and complexity generation from allenoates
2. Phosphine-Catalyzed Cycloaddition of 2,3-Butadienoates or 2-Butynoates with Electron-Deficient Olefins. A Novel [3 + 2] Annulation Approach to Cyclopentenes
3. Phosphine catalysis of allenes with electrophiles
4. Phosphine-Catalyzed [4 + 2] Annulation: Synthesis of Cyclohexenes
5. Asymmetric [3 + 2] Cycloaddition of 2,3-Butadienoates with Electron-Deficient Olefins Catalyzed by Novel Chiral 2,5-Dialkyl-7-phenyl-7- phosphabicyclo[2.2.1]heptanes
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1. Pyridine vs DABCO vs TBAB in Annulations of δ-Acetoxy Allenoates with Thioamides Leading to Dihydrothiophene, Thiopyran, and Thiazole Scaffolds;The Journal of Organic Chemistry;2022-01-04
2. Recent Advances in Lewis Base‐Catalysed Chemo‐, Diastereo‐ and Enantiodivergent Reactions of Electron‐deficient Olefins and Alkynes;The Chemical Record;2021-12-27
3. Recent advances in tertiary amine Lewis base-promoted cycloadditions of allenoates;Chinese Chemical Letters;2021-11
4. Mechanism, Chemoselectivity, and Stereoselectivity of NHC‐Catalyzed Asymmetric Desymmetrization of Enal‐Tethered Cyclohexadienones;European Journal of Organic Chemistry;2020-06-09
5. A theoretical review for novel Lewis base amine/imine-catalyzed reactions;Organic & Biomolecular Chemistry;2020
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