AGA8 supported Cu(I) nanoclusters as in situ generated catalysts for room temperature C‐S coupling reactions in water

Author:

Jin Hao12ORCID,Fan Yun12ORCID,Liu Penghao12ORCID,Meng Qi12ORCID,Teng Qiaoqiao12ORCID

Affiliation:

1. School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Changzhou University Changzhou China

2. Jiangsu Province Engineering Research Center of Biodegradable Materials Changzhou University Changzhou China

Abstract

A sustainable and green catalytic strategy for C‐S coupling reactions is developed by combining micelle and transition metal. The synergistic AGA8@Cu(I) catalyst forms by spontaneous anchoring of the in situ generated Cu(I) nanoclusters onto the AGA8 micelles and has been fully characterized by FT‐IR, XPS, SEM, TEM, EDS, and ICP‐OES. The catalyst is recyclable and highly effective in mediating the conversion of halides to disulfides in water at room temperature with a broad substrate scope.

Funder

National Natural Science Foundation of China

Changzhou University

Publisher

Wiley

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