Test method for vapor collection and ion mobility detection of explosives with low vapor pressure

Abstract

RationaleIon mobility spectrometry (IMS) has been widely used for on‐site detection of explosives. Air sampling method is applicable only when the concentration of explosive vapor is considerably high in the air, but vapor pressures of common explosives such as 2,4,6‐trinitrotoluene (TNT), 1,3,5‐trinitro‐1,3,5‐triazacyclohexane (RDX), and pentaerythritol tetranitrate (PETN) are very low. A test method for analyzing the vapor detection efficiency of explosives with low vapor pressure via IMS was developed using artificial vapor and collection matrices.MethodsArtificial explosive vapor was produced by spraying an explosive solution in acetone. Fifteen collection matrices of various materials with woven or nonwoven structures were tested. Two arrangements of horizontal and vertical positions of the collection matrices were employed. Explosive vapor collected in the matrix was analyzed using IMS.ResultsOnly three collection matrices of stainless steel mesh (SSM), polytetrafluoroethylene sheet (PFS), and lens cleansing paper (LCP) showed the TNT and/or RDX ion peaks at an explosive vapor concentration of 49 ng/L. There was no collection matrix to detect PETN vapor at or lower than 49 ng/L. For the PFS, TNT and RDX were detected at a vapor concentration of 49 ng/L. For the LCP, TNT and RDX were detected at vapor concentrations of 14 and 49 ng/L, irrespectively.ConclusionsThe difference in the explosive vapor detection efficiencies could be explained by the adsorption and desorption capabilities of the collection matrices. The proposed method can be used for evaluating the vapor detection efficiency of hazardous materials with low vapor pressure.