The Roles of Changes in Bonding vs. Packing Fraction in the Pressure‐Induced Acceleration of the Diels‐Alder Reaction-Reference-Cited by-同舟云学术

The Roles of Changes in Bonding vs. Packing Fraction in the Pressure‐Induced Acceleration of the Diels‐Alder Reaction

Published:1989-06 Issue:6 Volume:122 Page:1089-1094
ISSN:0009-2940
Container-title:Chemische Berichte
language:en
Short-container-title:Chem. Ber.

Author:

Firestone Raymond A.¹,Smith Graham M.²

Affiliation:

1. Medicinal Chemistry – Immunology and Inflammation Dept., Merck Sharp & Dohme Research Laboratories, P.O. Box 2000, Rahway, NJ 07065

2. Molecular Systems Dept., Merck Sharp & Dohme Research Laboratories, West Point, PA 19864

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cber.19891220614

Reference51 articles.

1. Presented at the Symposium on Diels‐Alder Mechanisms A.C.S. Meeting Akron Ohio June 6 1985.

2. Activation and reaction volumes in solution

3. Glossary: TS transition state; RC reaction coordinate; BEPH Bell‐Evans‐Polanyi‐Hammond; DA Diels‐Alder; IMV intrinsic molar volume; MV molar volume; RDS rate‐determining step; IΔV intrinsic volume of reaction; IΔV≠ intrinsic volume of activation; IMD intrinsic molar density; ES empty space; CPD cyclopentadiene; ECCE dimethyl acetylenedicarboxylate; MA maleic anhydride; DMB dimethylbutadiene; MVK methyl vinyl ketone.

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