Reactions with Aziridines, 45. – Arene Hydrides, 5. Reversibility of Carbonyl Attack on N ‐Benzoylaziridines Prior to Ring Opening by Carbanions. – Strong Influence of the Gegen Ion
Author:
Affiliation:
1. Pharmazeutisch‐Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 364, D‐6900 Heidelberg
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/cber.19881210721
Reference13 articles.
1. Reactions with aziridines. 43. Reactivity difference of cis-trans pairs: different behavior of stilbene oxides and activated stilbene imines
2. Intramolecular radical trapping in “set” ring opening of N-enoyl aziridines. A new mechanistic probe and a new synthesis of pyrrolidones.
3. Arene hydrides, 4. Reaction of anthracene hydride (anion of 9,10‐dihydroanthracene) with diaryl ketones. Base‐induced fragmentation of the carbonyl adduct
4. Reactions with aziridines. 33. Arene hydrides. Part 1. Highly regioselective ring cleavage of N-acylaziridines by "anthracene hydride" (anion of 9,10-dihydroanthracene). Intermediacy of a carbonyl adduct. Influence of nitrogen inversion on the ring opening
5. Umlagerungen von Aziridin-Derivaten
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1. Radical Anions and Radical Cations Derived from Compounds Containing CC, CO or CN Groups;PATAI'S Chemistry of Functional Groups;2009-12-15
2. The regioselectivity of the ring opening of 1-activated or nonactivated 2-alkoxycarbonyl or 2-cyanoaziridines by carbanions of the dicarbonyl compounds;Journal of Heterocyclic Chemistry;2009-03-11
3. Benzylic Fragmentation (BFR), an Aromatic Analogue of E1cB Including a Homolytic Variant, as either Nucleofugal or Homolytic Path to Aryl Stabilized Carbanions or Ketyls, respectively;Journal für praktische Chemie;2000-06
4. Nucleophilic ring opening of aziridines;J PRAK CHEM-CHEM ZTG;1999
5. Amidoethylation of Anthracene Hydride by N-Aroylaziridines: Inner-sphere Single Electron Transfer (SET) and Radical Coupling confirmed;Journal of Chemical Research;1998
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