Entwurf und Synthese neuer saurer Komplexone vom EDTA‐Typ
Author:
Affiliation:
1. Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard‐Domagk‐Str. 1, D‐5300 Bonn 1
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/cber.19821150310
Reference25 articles.
1. Vom Arenoanalogie-Prinzip zu den Heterocyclopolyaromaten
2. From the Principle of Areno-Analogy to Heterocyclopolyaromatic Compounds
3. Das Stereologie-Konzept: Neuartige saure Komplexone und ihre Kationselektivität
4. The Stereology Concept: Novel Acidic Complexones and their Selectivity towards Cations
5. New Macrocyclic Polyethers
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1. Double-coupling of dibromo arenes with aryltriolborates for synthesis of diaryl-substituted planar frameworks;Tetrahedron;2011-09
2. Self-Assembly of 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Formation of an Achiral Grid with Chiral Compartments;Angewandte Chemie International Edition;1999-02-01
3. Selbstorganisation von 1,1′-Biphenyl-2,2′,6,6′-tetracarbonsäure unter Bildung eines achiralen Netzes mit chiralen Einheiten;Angewandte Chemie;1999-02-01
4. Supramolekulare Phosphoryl-Übertragungsreaktionen, vermittelt durch Amidinium-Phosphat-Ionenpaarkomplexe;Liebigs Annalen der Chemie;1994-10-28
5. FDTA [1,1′‐ F errocendiyl d i(methyleneamino) t etra a cetate] – An Organometallic Relative of EDTA The tetrasodium salt of 1,1′‐ f errocendiyl d i(methyleneamino)‐ t etra a cetate (FDTA‐Na 4 ) – a relative of EDTA (ethylene d i‐amino t etra a cetate) – was prepared from the reaction of N,N′ ‐1,1′‐ferrocendiylbismethylenebis(pyridinium) chloride tosylate with tetramethyl iminodiacetate and subsequent saponification with NaOH/CH 3 OH. Potentiometric titrations were performed to determine the stability constants of the complexes of FDTA (= L) with the alkaline earth metal ions Mg 2+ , Ca 2+ , Sr 2+ , and Ba 2+ (β: brutto stability constants): MgL (log β = 4.63), MgL 2 (log β = 8.10), CaL (log β = 4.97), CaLH (log β = 14.20); SrL (log β = 3.91), SrLH (log β = 13.43), and BaL (log β = 3.06). The stability constants are discussed with a view to cooperative effects of the two iminodiacetate groups in FDTA. The nonexistence of M 2 L and ML 2 (M = Ca, Sr) species is considered indicative of a cooperative effect of the donor groups. The X‐ray crystal structure of FDTA‐Na 4 was determined.;Chemische Berichte;1993-12
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