Photopolymerization of polyvinylethylene glycol oligomers by thiol‐ene click reaction

Author:

Yang Fan12,Wang Minghang12,Zhang Yong Jian12ORCID

Affiliation:

1. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, and School of Chemistry and Chemical Engineering Shanghai Jiao Tong University Shanghai China

2. Sichuan Research Institute Shanghai Jiao Tong University Chengdu China

Abstract

AbstractFunctional polyvinylethylene glycols (PVEGs) with pendent vinyl groups were synthesized by Pd/B synergistic catalysts and their structures were characterized by 1H NMR and FT‐IR. The photopolymerization of the obtained PVEGs with multifunctional thiols in the presence of a photoinitiator proceeded smoothly via thiol‐ene photo‐click reaction to give a series of crosslinked materials by the variation of the molecular weight of PVEGs and a ratio of thiols and enes. The curing behavior was studied by FT‐IR and the properties of crosslinked materials were characterized by the test of gel content, swelling ratio, and water absorption. The dynamic mechanical analysis, mechanical properties, thermogravimetry, and surface properties of the crosslinked materials were investigated and the performance of coating for the crosslinked film materials was also characterized. The crosslinked film materials can be further functionalized by post‐crosslinking modification through thiol‐ene photo‐click reaction.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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