Comparison of the Nucleophilicities of Alkynes and Alkenes. Quantitative Determination of the Nucleophilicities of Alkynes toward Carbenium Ions
Author:
Affiliation:
1. Institut für Organische Chemie der Technischen Hochschule Darmstadt, Petersenstraße 22, 64287 Darmstadt, Germany
2. Institut für Chemie der Medizinischen Universität zu Lübeck, Ratzeburger Allee 160, 23538 Lübeck, Germany
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/cber.19941270311
Reference27 articles.
1. Relative ease of formation of carbonium ions and vinyl cations in electrophilic additions
2. Reactions in moderately concentrated acids. 2. Solvation effects in the acid-catalyzed hydration of olefins and acetylenes
3. Electrophilic additions to acetylenes. 7. Relative reactivity of double and triple bonds toward carbenium ions
4. Relative reactivities of carbon-carbon double and triple bonds toward electrophiles
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