Mesopore Catalytic Activated‐Carbon to Reduce Harmful Gases Indoors: Adsorption, Catalytic Oxidation, and Prediction Mechanism

Author:

Rengga Wara Dyah Pita1ORCID,Purwanto Widodo Wahyu2,Sudibandriyo Mahmud2,Nasikin Mohammad2

Affiliation:

1. Department of Chemical Engineering Universitas Negeri Semarang Semarang Indonesia

2. Department of Chemical Engineering Universitas Indonesia Depok Indonesia

Abstract

ABSTRACTModification of local bamboo‐based catalytic activated carbon with metallic Ag can produce mesopore and micropore types, with a mesopore content of 86%. One of the best ways to reduce formaldehyde concentrations is through catalytic adsorption. In combination with Ag nanoparticle catalyst, formaldehyde adsorption capacity is improved. Adsorption and oxidation reaction experiments are performed in a fixed bed column (di = 10 mm, length = 90 mm). The increase in formaldehyde adsorption associated with the reaction rate of formaldehyde oxidation by metallic Ag is 51 g/mmol. The oxidation reaction of Ag nanoparticles is a bimolecular reaction based on the Langmuir–Hinshelwood mechanism. Formaldehyde can be reduced by 59% and 41% through the role of adsorption and support of catalytic oxidation, respectively. Additionally, harmless gases such as CO2 and H2O are produced within the column.

Funder

Kementerian Riset, Teknologi dan Pendidikan Tinggi

Publisher

Wiley

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