Affiliation:
1. School of Materials and Mineral Resources Engineering Universiti Sains Malaysia Penang Malaysia
2. Department of Polymer Engineering National Textile University (Karachi Campus) Karachi Pakistan
3. School of Engineering & Technology National Textile University Faisalabad Pakistan
Abstract
AbstractPolymethylmethacrylate‐co‐methacrylic acid (PMMA‐co‐MAA) was utilized for surface improvement of silica to be used as reinforcement in self‐healing natural rubber based on metal thiolate ionic network. The amount of PMMA‐co‐MAA was varied at 1, 3, and 5 wt% of silica content and the optimized PMMA‐co‐MAA was utilized to investigate the self‐healing NR/silica composites at different filler loading (5, 10, 20, and 30 phr). The graft polymerization of PMMA‐co‐MAA on silica was confirmed using FTIR spectroscopy and grafting percentage was determined by thermogravimetric analysis (TGA). Intermolecular diffusion occurred at the fractured area was detected using a scanning electron microscope (SEM) and the results revealed that the composite tensile and tear performance increased 22%–70% with healing efficiency percentage ranging between 70% and 97% depending on the silica loading.
Subject
Materials Chemistry,Polymers and Plastics,General Chemistry,Materials Chemistry,Polymers and Plastics,General Chemistry
Cited by
2 articles.
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