Chlorination of isothiocyanates. VIII. Reaction ofS-chloroisothiocarbamoyl chlorides with aliphatic and cycloaliphatic ketones

Author:

Ottmann G.,Vickers G. D.,Hooks H.

Publisher

Wiley

Subject

Organic Chemistry

Reference12 articles.

1. Chlorination of Isothiocyanates. II. N-Aryl- and N-Alkyl-S-chloroisothiocarbamoyl Chlorides, a Novel Class of Sulfenyl Chlorides

2. Angew. Chem., 77, 427 (1965);

3. Angew. Chem. Intern. Ed. Engl., 4, 432 (1965).

4. The Sulfenic Acids and their Derivatives.

5. The possibility of an interaction of the imidoyl chloride portion of I with the ketone as initial reaction step was considered. Recent investigations (5,6) on compounds I and the failure of N,S-diphenyl isothiocarbamoyl chloride, C6H5N=C(Cl)SC6H5, to react with ketones under our conditions do not support this course of reaction.

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