Author:
Maso MÓNica Dal,Orelli Liliana,Perillo Isabel A.
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4. As expected, 1H-nmr spectra sharply show methylenes a and c as triplets at δ values of ca. 3.20 and 2.60 (Table I). Instead, the same methylenes in N-aroyl-N'-aryl-N-methyltrimethylenediamines 4 characteristically appear as broad signals [1]. While this finding was not explained at the time, signal broadening is attributable to slow rotation around the CON bond, as advanced for diacyl-derivatives of ethylenediamines [5].
5. High multiplicity in the proton magnetic resonance spectra of certain ethylene diamides,
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