Nuclear magnetic resonance studies of heteroaromatic systems. Methyl coupling of 2-substituted picolines, 2-pyridones and 2-pyridthiones

Author:

Bell Charles L.,Egan Richard S.,Bauer Ludwig

Publisher

Wiley

Subject

Organic Chemistry

Reference26 articles.

1. C. L. Bell, J. P. Shoffner and L. Bauer, Chem. and Ind., 1353 (1963).

2. J. A. Elvidge and L. M. Jackman, [J. Chem. Soc., 859 (1961)] have postulated that 2-pyridone possesses 36% of the aromaticity attributed to benzene, aromaticity being defined as the ability of an induced ring current to be sustained in a cyclic system due to the delocalization of the π-electrons. They measured the chemical shifts of C-methyl groups in a series of methyl substituted 2-pyridones and compared these to those of some non-aromatic models.

3. In a recent communication, J. A. Elvidge [Chem. Comm., 160 (1965)) has applied his method for the estimation of aromaticities of furan, thiophene and pyrrole.

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